Preparation and Catalytic Hydrodechlorination Property of Nano Bimetallic Catalyst Pd–Ni/γAl2O3–SiO2
نویسندگان
چکیده
Pd–Ni bimetallic catalyst supported on a composite carrier of γAl2O3 and SiO2 was prepared by chemical precipitation methodology enhanced with an ultrasonic wave. In the present paper, influence dispersant, carrier, time intensity dechlorination property catalysts obtained are investigated. The appearance, morphology structure were characterized using X-ray diffraction (XRD), scanning transmission electron microscopy (STEM), N2 adsorption–desorption isotherm photoelectron spectroscopy spectrometer (XPS). composition active gradients in tested inductively coupled plasma-atomic emission spectrometry (ICP-AES). metal dispersion mean particle size metallic phase also determined CO chemisorption. Results indicate that nano bimetal average 2.45 nm distribution range 1–7 can be effectively prepared, chlorine content shellac dechlorinated is 0.18 wt%, which lower than reported previous literature, indicating perfect catalyst.
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ژورنال
عنوان ژورنال: Catalysts
سال: 2022
ISSN: ['2073-4344']
DOI: https://doi.org/10.3390/catal12040370